5/9/2023 0 Comments Yasu rule engine![]() QuickRules BRMS platform provides advanced tools for business analysts and developers enabling business rule modeling, analysis, implementation and management with advanced tools for analysis and simulation of business rules. Blissfully unaware of what the future had in store - a future that was going to give him sleepless nights. YASU, a pioneer in the Business Rules Management Solutions (BRMS), provides business rules solutions for both Java and. Proud with the implementation, and the fact that he took his company to a level few insurance companies in India have managed to reach, Subramanian was beginning to rest on his laurels. "We used some of the resources from YASU to build the software and then when the IT team became proficient with it, it took over the project and is now taking care of the incentive schemes,' says Subramanian. YASU was just the perfect fit for ING Vysya Life.īut this was not a clear case of build or buy. Rules in 2009 and completely replace its existing rule engine. The search ended at the doorstep of YASU Technologies, a Hyderabad-based rules management systems firm. Sanitas went with QuickRules by Yasu Technologies to map. The company formed a cross-functional team, which comprised two to three people each from IT, business and sales support. We needed something that was rapidly configurable and would work with minimum IT resources," explains Subramanian. His last startup YASU Technologies was a leader in Business Rules Engine and was acquired by SAP in 2007. During his brief stint in Private Equity, he figured that he needed to get back to doing what he did best-washing bottle at exciting startups. Company Information Company Name: YASU TECHNOLOGIES INC Address: 1001 Bayhill Dr 2nd Fl City: San Bruno State: California Zip Code: 94066-3061. These were inflexible and did not meet our requirements in features, availability and modeling capabilities. Satish has over 22 years of experience most of it in building successful startups. "We evaluated ready-made packages in the market. But Subramanian was not sure where to go for a rules engine that would fit his requirements. It comes with productivity enhancements that detect errors and conflicts automatically. Subramanian and his team explored all the possibilities available in the market and then zeroed in on a rules engine - a novel concept for the insurance industry.Ī rules engine is a graphical business rules development environment that reduces maintenance and enhancement costs by cleanly separating business rules from application code.
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5/9/2023 0 Comments Kaleidoscope edge control![]() Any item that is returned more than 30 days after delivery.Any item not in its original condition, is damaged or missing parts for reasons not due to our error.CD, DVD, VHS tape, software, video game, cassette tape, or vinyl record that has been opened.There are certain situations where only partial refunds are granted (if applicable) To complete your return, we require a tracking number, which shows the items which you already returned to us. We also do not accept products that are intimate or sanitary goods, hazardous materials, or flammable liquids or gases. Perishable goods such as food, flowers, newspapers or magazines cannot be returned. ![]() Several types of goods are exempt from being returned. It must also be in the original packaging. To be eligible for a return, your item must be unused and in the same condition that you received it. If you have any questions regarding shipping or want to know about the status of an order, please contact us or email us at may return most new, unopened items within 30 days of delivery for a full refund. If your package has been delivered in a PO Box, please note that we are not responsible for any damage that may result (consequences of extreme temperatures, theft, etc.). You will be able to track your package at all times. Once your order has left our warehouse, a confirmation e-mail with a tracking number will be sent to you. Shipping method varies depending on what is being shipped.Īll orders are shipped with a tracking number. ![]() This period excludes delivery times, which depend on your geographic location. The usual time for processing an order is 24 hours (business days), but may vary depending on the availability of products ordered.
5/9/2023 0 Comments Bitdefender oem alliances![]() He started building the channel of resellers, chose the right distributors and showed a special interest to retail and OEM deals. Razvan implemented the distribution policy for the Romanian market in a very professional manner. A sales representative will contact you in maximum 48 hours. I met Razvan when we both used to work at BitDefender, in the same department, dealing with the Romanian market. BitDefender solutions are distributed by a global network of value-added. To evaluate our technology or learn more about our offering, just fill in the fields below. A summary of the hardware (IHV) and software (ISV) partners that support Oracle. You will receive an email notification before you will be billed, along with information regarding pricing and the extension of your subscription duration. Thank you for your interest in the Bitdefender Technology Licensing solutions. The prices are subject to change, but Bitdefender will send a prior notification by email, before the automatic renewal takes place. If a discount is presented, it describes the difference between the first term and renewal term subscription prices (e.g., first year price vs. Integrate Bitdefenders award-winning anti-malware technologies and threat intelligence in your cybersecurity products and services with our easy-to-use OEM.What is more unusual about the WatchGuard deal is Bitdefenders. After that, your subscription will be billed at the applicable renewal price which may be higher than the initial purchase price We have over 20 SDKs that we make available to OEM partners on a licensing business. For the past 18 years, our team has been creating award-winning technologies that you can now easily integrate in your own products or services. Trusted by Hundreds of Technology partners. The price offered is valid for the first year of subscription. OEM Technology Partnerships Proven by Countless Awards.24/7 security all-subscription long without interruption.Opt out at any time so that you are always in control of your renewal options.Save time while we are taking care of the automatic renewal process.Peace of mind that your devices are always protected Complete Solutions to protect your business and secure your computer from the latest viruses.Offers a variety of antivirus products, including specialized handheld device, peer-to-peer, and email scanners.We also receive and welcome vulnerability advisories via Bug Bounty programs, and support security vendor transparency in reporting. Bitdefender OEM Technology Partnerships For Home For Business For Partners Company Labs OEM Technology Partnerships Proven by Countless Awards. Allows partners to expand into new markets. Free upgrades whenever a new version of Bitdefender comes out As a trusted member of the security industry, Bitdefender continually assesses our own products. Here are some of the reasons why OEM partners choose Bitdefender: Generates additional revenue by offering antivirus engine to customers. ![]() ![]() Continuous protection so that you never have to worry about your subscription running out before you renew manually.Bitdefender GravityZone SVE, a VMware Ready solution, delivers award-winning layered next-generation defenses to protect server and VDI workloads running in vSphere, NSX, and VMware Cloud on AWS environments, while enabling efficient centralized security management and improving infrastructure utilization, performance and end-user experience. security products, Bitdefender is best known for their OEM business. Focused on helping partners combine managed services expertise and. The top endpoint security solutions include: CrowdStrike, Bitdefender, Eset. Bitdefender Central GravityZone CLOUD Control Center. VMware software spans compute, cloud, networking and security, and digital workspace.Īs a VMware Elite Technology Alliance Partner, Bitdefender has collaborated with VMware for many years, becoming the first to support VMware NSX-T Data Center and, earlier, NSX Guest Introspection for Linux. Robert Sawyer and Daniel Daraban of Bitdefender Become Your Customers Strategic. Log in to your Bitdefender account and manage security for what matters. VMware streamlines the journey for organizations to become digital businesses that deliver better experiences to their customers and empower employees to do their best work. 5/9/2023 0 Comments Wild rumpus 2021The event is free and open to the public Everyone in a costume can be in the parade. Every dollar you give helps fund our ongoing mission to provide Athens with quality, independent journalism. The Wild Rumpus is on Saturday, October 29th, 2022. Like what you just read? Support Flagpole by making a donation today. Much respect to Timi Conley.Ĭheck out photos from the event below, courtesy of Lee Shearer: Lee Shearer Lee Shearer Lee Shearer Lee Shearer Lee Shearer Lee Shearer Lee Shearer Lee Shearer Lee Shearer Lee Shearer Sam Lipkin Lee Shearer Lee Shearer Lee Shearer Lee Shearer Lee Shearer Lee Shearer Lee Shearer Lee Shearer Lee Shearer Lee Shearer Lee Shearer Founded in San Francisco by composer Jen Wang in 2011, the ensemble brought together stellar musicians who share a passion for risk-taking, collaboration, and working with living composers. 2021 Wild Rumpus attracts large crowd to party in the streets of downtown Athens. Afterward, when the parade ended at the 40 Watt Club, they could see trapeze artists perform in the eerie light and dancers with colorful lighted capes whirling through what seemed like thousands of people. Wild Rumpus was a contemporary chamber music ensemble dedicated to performing the music of the present. The Wild Rumpus returned to the streets of downtown Athens on Saturday and drew one of the events largest. People began gathering on Hancock Avenue at Creature Comforts Brewery hours before the parade-children watching in wide-eyed wonder as fire-dancers twirled their flaming sticks and weird monsters rumbled past. The annual Halloween party and parade felt like a joyful celebration for the costumed crowd of many ages perhaps a breakout from the chains of COVID. It is one of the Southeast’s premier Halloween celebrations and one of Athens’ most-loved festivals. 22, 2021 The Wild Rumpus is a large-scale crowd-participation Halloween holiday, music and arts celebration in downtown Athens, GA. After a one-year COVID hiatus, the Wild Rumpus Parade and Spectacle came back to downtown Athens Saturday night with more than a thimbleful of magic. Wild Rumpus Returns to Downtown Athens in 2021 By Partner Release on Oct. ![]() The miner uses one of three clients to connect to the Ethereum network: Geth, Eth, or Pyethapp. With that in mind, miners typically focus on GPU processing. While CPUs can be used, GPUs have a much higher hash rate, or speed of computing hash functions than CPUs. Once the network passes a certain size and is widely distributed, this becomes impractical enough to be considered impossible.Įach miner on the network needs three things to be successful: A very large network of miners is needed to prevent this risk of fraud and corruption. In order to hack or rewrite blocks, a malicious agent would need to control at least half of the Ethereum network of miners. While the Ethereum network does not want collisions, in practice each miner would love to detect one. In the cryptocurrency world, if a collision is detected then the algorithm used to create the collision is abandoned in favor of one which is more complex and secure.īecause of the threat of collisions, a bounty is placed on detecting them. Think of this as two cars attempting to use the same parking space at the same time.īecause of the risk of collisions and the need to ensure data security, hash functions for mining operations are complex and require significant computational power. CollisionsĪ collision occurs when two different sets of data calculate the same checksum or hash function. This is the cryptographic element of cryptocurrencies and is used to ensure anonymity. ![]() Hash functions are then collected into hash tables, which can be used to quickly organize and sort data records.īecause of the nature of hash functions, algorithms can be built that will ensure the original data set cannot be reproduced from the hash function itself. It also ensures no accounting errors or ledger mistakes can occur.Ī hash function is a checksum algorithm that converts data files of arbitrary size to a data string of fixed size. In cryptocurrencies, checksums are used to make sure that once you spend your coin, everybody knows you have spent it and you can’t spend it again. If even one bit of the original data set is altered, the checksum will be altered, alerting the system to an error.Ĭhecksums are used in many computer programming situations when data is transferred or stored and there is a risk of data corruption. ![]() Hash FunctionsĪll hash functions are checksums, but not all checksums are hash functions.Ī checksum is a calculation that represents a large data set with a smaller, unique data set used to detect errors in data transmission or storage. Once validated, a new block is connected to the chain of all previous blocks and is then said to be integrated into the blockchain. Let’s take a closer look at each of these elements below.Ī blockchain is a massively distributed set of dynamic records and is essential for cryptocurrency trading.Īs records accumulate, they are collected into blocks and validated.
5/9/2023 0 Comments Windows 8.1 disc image tools![]() Refer to the following message from Ubuntu's mailing list if you want to learn more. Warning: The driver descriptor says the physical block size is 2048 bytes, but Linux says it is 512 bytes.Īll these warnings are safe to ignore, and your drive should be able to boot without any problems. Next, choose whether you want the 32-bit or 64-bit version of Windows 7. C:WINDOWSsystem32>schtasks.exe /Run /TN 'MicrosoftWindowsServicingStartCom. A window appears in which we have not changed anything yet. After your product key is verified, select the product language you want to download and then click Confirm. Expand the console tree and navigate to Task Scheduler LibraryMicrosoftWindowsServicingStartComponentCleanup. ![]() Try making a fresh table, and using Parted's rescue feature to recover partitions. If you do have a valid retail key, head to the Windows 7 download page, enter your product key, and click Verify to start the download process. Is this a GPT partition table? Both the primary and backup GPT tables are corrupt. Select MBR partition style only when you intend to use image-cloning tools or third party disk-management tools that require an MBR partition for compatibility. Or perhaps you deleted the GPT table, and are now using an msdos partition table. ![]() Perhaps it was corrupted - possibly by a program that doesn't understand GPT partition tables. However, it does not have a valid fake msdos partition table, as it should. dev/xxx contains GPT signatures, indicating that it has a GPT table. Ubuntu images (and potentially some other related GNU/Linux distributions) have a peculiar format that allows the image to boot without any further modification from both CDs and USB drives.Ī consequence of this enhancement is that some programs, like parted get confused about the drive's format and partition table, printing warnings such as: 5/9/2023 0 Comments Applause synonyms![]() Waiting until an exultant roar of applause had died away, he delivered his most effective hit. When he came out on the stage the applause was tremendous, and enough in itself to excite and electrify one.Ī boy on the stage danced very finely and obtained much applause.Ī hideous yell of applause rose from the multitude, and again he plunged his saber into the carriage. General Lachambre, as the hero of Cavite, followed to receive the applause which was everywhere showered upon him in Spain.įrantic applause, several times repeated, which drowned the voice of the orator. It connects directly to a smartphone and allows wannabe broadcasters to add effects like applause and musical cues to their productions.ĭíaz-Canel, therefore, did not have to win the applause of the masses with government proposals. (of a performance) to be received with silence rather than applause. She also, according to Republicans in the room, apologized for putting her colleagues in a difficult spot - prompting a round of applause. DIED in Thesaurus: 100+ Synonyms & Antonyms for DIED Synonyms Similar meaning View. These synonyms for the word applause are provided for your information only.When Stewart walks into an upscale Pittsburgh steakhouse with a female date, the other diners erupt in applause - a standing ovation because he’s out on the town with a woman. is more than 70,800 synonyms and 47,200 antonyms available. This site allows you to find in one place, all the synonyms and antonyms of the English language. In your daily life, for writing an email, a text, an essay, if you want to avoid repetitions or find the opposite meaning of a word. Plaudit is a shout of applause, and is commonly. The words blockage, encumbrance, handicap are antonyms for "help". Acclaim is the more poetic term for acclamation, commonly understood in a loftier sense as, a nations acclaim. The words acknowledge, enjoy, welcome are synonyms for "appreciate". 693 other terms for applause- words and phrases with similar meaning. Antonyms are used to express the opposite of a word. Another way to say Applause Synonyms for Applause (other words and phrases for Applause). Antonym definitionĪn antonym is a word, adjective, verb or expression whose meaning is opposite to that of a word. This avoids repetitions in a sentence without changing its meaning. Synonyms are other words that mean the same thing. ![]() Extract from : « The Harbor » by Ernest PooleĪ synonym is a word, adjective, verb or expression that has the same meaning as another, or almost the same meaning.Usually to show approval of something (see: applaud). The little man's speech was greeted with a sudden roar of applause. To strike ones own palms together, creating a distinct sound.Extract from : « White Fang » by Jack London.Shouts of applause went up for the victor, and there were many cries of “Cherokee!”.Extract from : « A Woman Intervenes » by Robert Barr.This was received with applause, and the meeting terminated.Extract from : « Freeland » by Theodor Hertzka Self-stimulatory behavior, also known as stimming and self-stimulation, is the repetition of physical movements, sounds, words, moving objects, or other.Here the speaker was interrupted by applause that lasted several minutes.Croizette had just played her part, and her kiss had been greeted with a burst of applause.Victor Hugo finished his speech in the midst of applause and cheers. ![]() Extract from : « My Double Life » by Sarah Bernhardt 32 synonyms for applause: ovation, praise, cheering, cheers, approval, acclaim, clapping. Synonyms for APPLAUSE: clapping, kudos, acclamation, bravos, approval, eulogy, plaudit, esurience, ovation, acclaim, celebration Antonyms for APPLAUSE.When I came on to the stage I was always greeted by applause from these young men.Extract from : « It Happened in Egypt » by C.On the tide of applause which congratulated the boat's only baronet, I rose.Extract from : « The Foolish Lovers » by St.Her applause was not languid applause, neither was it without discrimination.Extract from : « A Sketch of the Life of Brig.This short speech was received with applause by the combatants. 5/9/2023 0 Comments Handy manny mr lopart![]() Manuel "Manny" Garcia (voiced by Wilmer Valderrama) - The bilingual Hispanic/Mexican handyman, and the handiest handyman in all of Sheetrock Hills.Once they have the items needed for the repair, they go back to the work site and sing "We Work Together" while performing the repairs.Ĭharacters Human characters Main human characters Manny then goes to Kelly's hardware store, where she always has the item that they need. Once Manny and the tools arrive at the repair site, they collaborate on the best way to fix the broken item. Lopart was building would malfunction and cause a mess. Lopart says that he doesn't need any help after Manny and the Tools leave, the item Mr. Lopart would try to do something on his own without any prior experience. Lopart with his pet cat Fluffy in front of his candy store. When Manny and the Tools leave for the repair in most episodes, they see Mr. After hearing who needs help and where the location is, Manny and the Tools sing "Hop up, Jump in" while the Tools hop into his toolbox. ![]() While there, someone, usually needing something repaired or assembled, calls Manny, who answers, "Hola, Handy Manny's repair shop, you break it," and then the tools shout, "We fix it". They typically begin with Manny and the tools interacting in Manny's repair shop. Most 30-minute episodes contain two stories. It is unknown exactly where this town is located, but due to the multitude of Spanish speakers and the town's location being in a desert, it may be Arizona. Handy Manny is set in the fictional town of Sheetrock Hills, a play on the genericized trademark for drywall in the United States, where the titular character, Manny, owns a repair shop along with his anthropomorphic talking tools. 3.4 Other businesses outside Sheetrock Hills.Reruns are being shown on certain days on Disney Junior. The theme song is performed by Los Lobos. Special guest stars in the series have included Lance Bass, Kurtwood Smith, Shelley Morrison, Fred Willard, Penn Jillette, Jane Lynch, Jon Polito, Ashley Parker Angel, Brian George, Snoop Dogg, Shannon During, Marion Ross, Chris Rock, James Belushi, Ice-T, Henry Winkler, Dale Earnhardt, Jr., and Bob Glouberman. The animation is produced by Toronto-based Nelvana and features the voice performances of Wilmer Valderrama, Dee Bradley Baker, Tom Kenny, Fred Stoller, Nika Futterman, Kath Soucie, Carlos Alazraqui, and Grey DeLisle. The show was created by Roger Bollen, Marilyn Sadler, and Emmy Award-winning writer and producer Rick Gitelson. Many kids 4-8 are usually the show's audience. A bilingual French version premiered in Canada on Jon Teletoon alongside the original version. ![]() It also teaches young children the beginnings of Spanish and the importance of cultural diversity. The show features Wilmer Valderrama who plays Manny Garcia, a bilingual Hispanic handyman, and his anthropomorphic tools. On February 14, 2011, it was moved to the Disney Junior block, serving as Playhouse Disney's replacement. The program was originally part of the Playhouse Disney daily block intended for preschoolers. Source Handy Manny is a Disney computer-animated children's television program that premiered on September 16, 2006. Handy manny (play on the word handyman) manny, owns a repair shop along with his anthropomorphic talking tools.Septem– FebruExternal links Official website Handy manny is set in the fictional town of sheet rock hills where the titular character, manny, owns a repair shop along with his anthropomorphic talking tools. He is a citizen of sheetrock hills and he is the owner and manager of his own store, mr.Īnyways i rewatched handy manny and i forgot how smart the show was. This character doesn't have any uploaded avatars :( members married to mr. He is currently in a relationship with emmanuel mahgrefta. Lopart is one of the main characters who appears in handy manny. She has appeared in almost every episode. Lopart from handy manny played by tom kenny by mikejeddynsgamer89 on deviantart.įor manny, his tools are no less than his family. Slightly campy owner of a candy store next to manny's workshop. Leonard francis lopart (refered to as mr. Lopart deliver the packages to the mailbox. In each episode when manny and the tools leave for the repair, they see mr. He is a citizen of sheetrock hills and he is the owner and manager of his own store, mr.ĭon't forget to subscribe for more videos !! He has had them since he was just a child and has been fixing things up using their help for such a long time that they could not be seen otherwise. ![]() 5/9/2023 0 Comments Burger king nuggets![]() We're excited to hear what our guests in the test markets think of this latest innovation." "So it's only fitting we're the first global QSR to test the Impossible Nuggets. In 2019, we became the first quick-service restaurant to serve the award-winning, plant-based Impossible patty and offer the iconic Impossible Whopper," said Ellie Doty, Burger King North America's chief marketing officer, in a statement. "This isn't the first time we have teamed up with Impossible to make waves in the industry. ![]() Related: San Antonio–based Project Pollo aims to upend chicken industry with new plant-based product Next week, guests in Des Moines, Iowa Boston and Miami will be able to try Burger King’s version of the chicken-free nuggets, which are already being rolled out by smaller chains following the foodservice debut of the Impossible product last month. Investors include Khosla Ventures, Bill Gates, Google Ventures, Mirae Asset Global Investments, Coatue, Horizons Ventures, UBS, Viking Global Investors, Temasek, Sailing Capital and Open Philanthropy Project.Burger King is testing the new Impossible Foods nuggets in several markets, following the success of the plant-based Whopper. Brown, M.D., Ph.D., Professor Emeritus of Biochemistry at Stanford University and a former Howard Hughes Medical Institute investigator. The privately held company was founded in 2011 by Patrick O. To learn more about the Burger King brand, please visit the Burger King brand website at or follow us on Facebook, Twitter, Instagram and TikTok.īased in California’s Silicon Valley, Impossible Foods makes delicious, nutritious meat and dairy products from plants - with a much smaller environmental footprint than meat from animals. Almost 100 percent of Burger King restaurants are owned and operated by independent franchisees, many of them family-owned operations that have been in business for decades. The Burger King system operates more than 18,700 locations in more than 100 countries and U.S. Terms apply: bk.com/rewards-terms.įounded in 1954, the Burger King ® brand is a global fast-food hamburger chain known for food quality and value as the only place guests can get the flame-grilled Whopper® and the hand-breaded Ch’King™ sandwiches. Earn 10 Crowns for every $1 spent at a participating restaurant (before discounts, after applicable taxes and fees). Account registration required on the BK ® App or BK.com. **Royal Perks available at participating U.S. Impossible™ and "Impossible Nuggets™" are trademarks of Impossible Foods, Inc. Impossible Nuggets™ are made from plants and cooked in the same oil as meat and cheese products. restaurants in Des Moines, IA, Boston, MA and Miami, FL. ![]() *Available for a limited time only at select U.S. Go ahead, sign up for Royal Perks to get in on the Ghost Pepper Chicken Nuggets before everyone else, redeem new member deals this month, and start earning on your first order today on the BK ® app or. Our Royal Perks members can earn 10 Crowns for each $1 spent on their purchases**. This is the first time we’re giving our loyal members an exclusive first look to a brand-new menu item, and it won’t be the last. Our Royal Perks members will have exclusive access to be the first to unlock and try Ghost Pepper Chicken Nuggets today in the BK ® app, before they’re available to everyone else on Oct. Made with white meat chicken kicked up with fiery ghost pepper, Ghost Pepper Chicken Nuggets are the perfect balance between flavor and heat. We’re excited to hear what our guests in the test markets think of this latest innovation.”Īnd the nugget innovation doesn’t stop there – we’re also rolling out new Ghost Pepper Chicken Nuggets nationwide for a limited time only. “So, it’s only fitting we’re the first global QSR to test the Impossible Nuggets. In 2019, we became the first quick-service restaurant to serve the award-winning, plant-based Impossible patty and offer the iconic Impossible Whopper,” said Ellie Doty, Chief Marketing Officer, Burger King North America. “This isn’t the first time we’ve teamed up with Impossible to make waves in the industry. 11, available in an eight-piece order with your choice of dipping sauce. ![]() Our guests in Des Moines, IA, Boston, MA and Miami, FL will get a first taste of Impossible Nuggets made from plants* starting Oct. Burger King will be the first global quick-service restaurant brand to test the plant-based nuggets from Impossible Foods that have the savory taste of a family favorite, with a golden-brown crispy breading on the outside and a tender, juicy bite on the inside. MIAMI-( BUSINESS WIRE)-You come to BK to have it your way – whether that’s the iconic flame-grilled Whopper ®, the hand-breaded Ch’King™ sandwich, or one of the exciting new innovations on our menu like the Impossible™ Nuggets Made From Plants. 5/9/2023 0 Comments Lumo and humo![]() Thus, red represents negative regions and blue represents positive regions on an electrostatic potential surface. The electrostatic potential is typically "painted" on the electron density isosurface.īy default WebMO represents smaller values by red and larger values in blue. The electrostatic potential is the energy that a unit charge at each point in space would have due to the surrounding electrons and nuclei, which is computed by integrating the electron density divided by distance at each point in space. The electron density isosurface represents the size and shape of the molecule. The electron density is computed from the sum of squares of occupied molecular orbitals. Interpreting Molecular Orbital Imagesīy default WebMO represents occupied orbitals in red/blue and unoccupied orbitals in yellow/green. When the Orbitals list is displayed in the Molecule Viewer, clicking on any particular orbital will display it. The orbital zoom is controlled by choosing View:Zoome ( ) and dragging vertically. The location of the orbital is controlled by choosing View:Translate ( ) and dragging vertically. The orientation of the orbital is controlled by choosing View:Rotate ( ) and dragging in the x-y plane or alt-dragging horizontally for z-axis rotation. The orbital definitions (basis functions and linear combination coefficients) may be saved locally by clicking the Download icon ( ). The electron density, electrostatic potential, and electrophilic/nucleophilic/radical frontier densities may also be displayed. Individual orbitals may be displayed by clicking the corresponding View icon ( ). The symmetry, occupancy, and energy of each orbital is tablulated in the Molecular Orbitals section of Calculated Quantities. Molecular orbitals and related quantities are displayed on the View Results page in the Molecule Viewer tab of the 3-D visualizer. Hence, smaller HOMO-LUMO gaps correspond to better stability.When a job has completed, from the Job Manager page click either the job name or the View Job icon ( ). The greater the mobility of the #pi# electrons in large conjugated pi orbital systems, the greater the distribution of the energy throughout the molecule, stabilizing it. When you have a large aromatic system in particular, small HOMO-LUMO gaps lead to mobile #\mathbf(pi)# electrons since it is easy for the electron to jump to a higher energy level that is close in energy. ![]() The larger the aromatic system is, the smaller the HOMO-LUMO gap! Hence, it is the most important energy gap to consider.Įxcitations becomes easier as the HOMO-LUMO gap converges, such as for large aromatic systems (like tetracene or benzopyrene), or for transition-metal complexes (that is why they tend to be colored). That means they are closest in energy out of all orbitals in the molecule.ĭue to the energies of these orbitals being the closest of any orbitals of different energy levels, the HOMO-LUMO gap is where the most likely excitations can occur. ![]() Of the orbitals that have electrons, the HOMO is the highest in energy, and of the orbitals that don't, the LUMO is the lowest in energy. Don't be confused though, because the LUMO is higher in energy than the HOMO. HOMO stands for " Highest Occupied Molecular Orbital", and LUMO stands for " Lowest Unoccupied Molecular Orbital". |